Here is something I copied from Circuitnet.com. This appears to answer your question and then some... http://www.circuitnet.com/experts/
Ask the Experts Jul 17, 2006
What type of cleaner method is preferred for lead-free stencils? What type of stencil cleaner is preferred: ultrasonic or high pressure jet? The application is in lead free cleaning of stencils after screen printing.
Ask the Experts Comments:
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This is a good opportunity to let everyone know that the IPC has been working on a Handbook for Stencil and Misprinted Board Cleaning. The final draft was submitted in early June and hopefully the document (IPC-7526) will be released soon.
The decision process for selecting a system for cleaning lead-free is the same for lead/tin solder paste.
There are several factors to consider when selecting a stencil cleaner. Most experts will agree that the most important factor is the chemistry. The machine used to apply the chemistry is secondary. Washing greasy hands is a good analogy. Using a facial soap is usually not very effective, even with hard scrubbing and hot water. However, if a good hand cleaner is used, mild scrubbing is only required. The �soap� = the chemistry and the �scrubbing� = the machine.
Aside from cleaning efficiency, other factors to consider include:
Can the process potentially damage the stencil? Is the process also used for cleaning misprinted PCBs? What is the environmental impact? User safety? Versatility?
The best article I have seen written on the subject is �SMT Stencil Cleaning: A Decision That Could Impact Production� by Richard S. Clouthier. Mr. Clouthier, of Xerox when the article was published, reviews several different chemistries and cleaning technologies. We keep a copy of this and other pertinent articles on our web site: http://www.smartsonic.com - click on the �Recommended Reading� link.
Can the process potentially damage the stencil? Stencils are heat-sensitive. The epoxy glue that bonds the screen to the frame and metal-etched foil is cured at approximately 60 degrees C (140 F). If a stencil is washed in hot water or dried with hot air, the bond will weaken and eventually fail.
In addition, stainless steel has a very poor memory. Once it expands, it does not like to contract back to the exact same position. Therefore, fine-pitch apertures can become distorted and miss registered if the stencil is consistently exposed to heat.
The Clouthier article illustrates how delicate land mass areas, between fine-pitch apertures, can bend from the impact of high-pressure air or high pressure water jets, so air knives and high pressure water jets should be avoided.
Is the process also used for cleaning misprinted PCBs? The Clouthier article uses the term �Solder Ball Nightmare� when attempting to clean misprinted PCBs with spray jet technology. The sprays will broadcast the solder balls throughout the process chamber and contaminate the populated side �A� of a reflowed board.
Ultrasonic technology will not broadcast the solder balls. The solder balls fall away from the board by gravity. So, if the board is oriented properly (populated side up), the solder balls will not contaminate to populated side.
Studies by GEC Maroni and the EMPF Laboratory are summarized in an article by William Kenyon, �Why Not Ultrasonic Cleaning?� (http://www.smartsonic.com/article.html) Mr. Kenyon stresses the importance of High Ultrasonic Frequency and Low Power Density when cleaning PCBs. Using the analogy of scrubbing with a brush, the Ultrasonic Frequency = the type of brush and the Power Density = the amount of pressure used on the brush. Common ultrasonic frequencies range from 20 kHz up to 68 kHz. Most all ultrasonic stencil cleaners use 40 kHz, which has been shown to be safe and effective for cleaning PCBs and stencils. The frequency is normally modulated +/- a few kHz to eliminate �hot spots� in the cleaning bath (referred to as �sweep� or �variable� frequency).
Low ultrasonic frequency (20 kHz) = a wire scrub brush High ultrasonic frequency (68 kHz) = a soft tooth brush Low power density = holding the brush lightly with one hand High power density = holding the brush strongly with two hands
The Power Densities of stencil cleaners can vary tremendously. Mr. Kenyon�s article indicates approximately 10 watts / liter (amount of ultrasonic energy directed into the bath / amount of wash solution in the bath) as being safe. Many ultrasonic stencil cleaners use power densities of 15 w/l or greater. This is more than 50% higher than the recommended safety limits. The higher power densities are normally dictated by the chemistry used. Less effective chemistries require more scrubbing energy and therefore higher power densities.
What is the Environmental Impact? Biodegradable and VOCs (Volatile Organic Compounds) are the two key variables. Many of the popular aqueous chemistries are biodegradable. However, many still have a high VOC content. The latest VOC standard set forth by the South Coast Air Quality Management District�s Clean Air Solvent (CAS) Program is less than 25 grams per liter. Chemistries containing VOCs greater than 25 grams per liter are disallowed by California�s Rule 1171. Other states and countries have or will soon have similar restrictions.
User Safety? Flammable solvents such as alcohol have been the cause of several fires and explosions when used in a stencil cleaner. Static charges, the mechanical spark of a spray nozzle hitting a metal stencil and nearby electrical equipment have been the sources of ignition.
Noxious odors of some cleaning solutions can cause illness and employee discomfort.
Versatility? Can the process clean a broad spectrum of solder pastes or just the current flux type in use? If a new flux is introduced, will the process support the change? Newly introduced chemistries will not have the necessary track record. If a company has needed to introduce new formulations over the years to keep up with current flux technologies, the newest and greatest formulation from that company should be suspect. If the chemistry needs to change, the waste management and possibly the machine will also need to change starting the selection process for new equipment all over again.
If cleaning lead and lead-free solder pastes, are two separate machines required? Traces of lead will be present in the form of fugitive solder balls or lead ions in any stencil cleaner used for cleaning lead solder paste, so the potential of lead contamination onto a lead-free stencil is always present. Solder paste is broadcast throughout and adheres to the side walls and plumbing of the chamber of a spray technology stencil cleaner and ions often flow through micron filters. Lead ions will also be found in the wash solution of an ultrasonic machine. The key element to determine if two separate machines are required is the rinsing ability of the chemistry. Surfactants (detergents) tend to rinse easily and thoroughly. Saponifiers and solvent-based chemistries usually require longer rinse cycles.
In summary, first select a broad spectrum, non-flammable and low VOC chemistry that rinses easily. If using a spray jet technology and are also cleaning misprinted PCBs, be aware of potential solder ball contamination and use low spray pressure for cleaning delicate stencils. If using ultrasonic technology, orient misprinted PCBs properly to prevent solder ball contamination of reflowed components and use the highest ultrasonic frequency and lowest power density to effectively clean. Make sure that the chemistry manufacturer and the machine manufacturer guarantee the complete process else, if it fails to perform properly, support will be difficult.
Bill Schreiber, President Smart Sonic Corporation
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