It�s reasonable to want to understand this strange looking fabrication, before moving on to other issues.
Before moving on to that, tell us more about your thinking the silicon being from the BGA package. What kind of plastic package is this?
Describe [eg, texture, color, etc] the surface that failed to solder.
What level of potassium did your analysis show?
You are almost certainly not picking up pure silicon, the element. You could be picking up a compound of silicon, which could even be glass. Thing to consider are: * Does your fab use presses to laminate rigid boards, which have glass fiber reinforcing them?? * Could it might be residue from a pumice scrub that�s embedded into the pads. * Could it be a silicon based anti-foam that was not rinsed from the pads properly. * Some desiccants give off a silicon oxide vapor. Is this inhibiting your soldering operations? * May be the compounds are organic silicon compounds, silicones. [As a sailors, we used to go see Carol Doda, now high school girl use the stuff.]
How do you think your problem relates to the "black pad" problem in ENIG?
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