Hi Bob
Ideas to consider are: * Use your handheld XRF * Swab vinegar on the copper and watch it brighten * Use the following procedure
Nearly all copper minerals can be dissolved by melting with a mixture 1:2.5 of ammonium chloride and ammonium nitrate on a magnesia furrow. This melt is dissolved in a rather concentrated solution of ammonium carbonate, a deep blue colour indicates the presence of copper. Even small amounts are detected in this way if the solution is transferred to a small test tube; by looking in the axial direction from top to bottom the colour perception is independent of the height of the solution column. Identification is impaired by the presence of Ni, because Ni also causes a light-blue coloured solution with ammonium carbonate. To avoid any uncertainty some of the blue solution is brought to an acid reaction by acetic acid, and a solution of potassium ferrocyanide K4Fe(CN)6 is added. A brown precipitate indicates the presence of copper. Zinc ferrocyanide paper may be used instead. It should be mentioned that many secondary copper minerals are soluble in ammonium carbonate solution, e.g. malachite, azurite, all basic sulphates, phosphates, chlorides, and the copper silicates chrysokolla and dioptase. The dissolution rate of Cu-silicates is enhanced by the addition of ammonia solution. [Quick assays in mineral identification: A guide to experiments for mineral collectors and geoscientists in field work, Walter A. Franke, retired Professor of Mineralogy, Freie Universität Berlin, Germany]
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