Todd,
All liquid coatings are Newtonian - they follow gravity so they do indeed run away from sharp leads and edges. Silicones are generally worse because they have very low surface energy - although this is an asset when trying to get under components.
Very thin edge coverage does not necessarily equate to poor protection, unless you have proved that this is an area of circuit failure.
Is your silicone heat curable? Is it solvent based? Can you switch to an alternative?
One trick I know, is to pre-heat the assembly to around 120F immediately before coating. This way a solvent based coating or heat curable will be able to "FLASH" dry onto edges more effectively. Spray application will also help this greatly - not robotic dispensing, like Nordson Select-coat, but standard atomised spraying and then applying many "light" coats.
Hopes this helps, but let me know directly off line if you want more.
regards, Graham
And thanks to Dave F for alerting me.
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